Binuclear Structure of Copper(II) 2-Pyridinolate Complex
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چکیده
منابع مشابه
PREPARATION AND MOLECULAR STRUCTURE OF 2-BENZYLAMINOPYRIDINE COPPER(1) COMPLEX
2-Benzylaminopyridine (HBAP) reacts with NaH in THF and generates the sodium salt (NaBAP). Further reaction of [Cu(TMEDA) ] [CuCl ] with one equivalent of this ligand in THF leads to the formation of a dimeric Cu(1) complex, [Cu (BAP)] . H 0. The molecular structure has been determined by using a single-crystal X-ray diffraction method. The yellow compound crystallizes in the monoclinic s...
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A symmetric complex [NiL2(H2O)2]Cl2, where L = 2-picolylamine was synthesized and characterized by spectroscopic and structural methods. Single crystal X-ray studies reveal that the Ni(II) center located in a pseudo-octahedral N4O2 environment with bidentate ligands L positioned in basal and two water molecules in the apical position. The complex is solvatochromic, ionochromic and thermochromic...
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A new binuclear complex of [{NiCl(6-mbipy)}2(μ-Cl)2] (1) was prepared from the reaction of NiCl2.6H2O and 6-methyl-2,2'-bipyridine (6-mbipy) in a mixture of methanol and acetonitrile. Suitable crystals of 1 for X-ray diffraction measurement were obtained by slow evaporation of the resulted green solution at room ...
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The copper(II) complex [Cu(pic)2]·2H2O was synthesized with 2-picolinic acid (Hpic) and copper acetate as reactants by room temperature solid-solid reaction. The composition and structure of the complex was characterized by elemental analyses, single crystal X-ray diffraction, X-ray powder diffraction, FT-IR spectroscopy and thermogravimetry-differential scanning calor...
متن کاملCrystal structure of a binuclear polymeric self-assembled lead(II) complex.
A polymeric self-assembled complex [[Pb(pydc)(pydc-H2)(H2O)2]2]n is prepared from the complexation of a novel pyridine containing self-assembling system, LH2, [pyda-H2]2+[pydc]2- (pyda = 2,6-pyridindiamine and pydc-H2 = 2,6-pyridinedicarboxilic acid) and lead(II) nitrate in 84% yield. The characterization was performed using X-ray crystallography. The crystal system is triclinic with space grou...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1972
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.45.3717